The CE Discussion Group is a working group of the Section Analytical Chemistry of the Royal Dutch Chemical Society (SAC-KNCV). It is a platform for users (or interested members) of electrophoretic separation methods with broad open discussions in practicalities, theory, technology and applications. The group comprises of academics, industrial and clinical users, students, and peers. The group aims to organize at least one meeting per year (virtual or in-person). Presentable topics vary from new technological advances, theoretical insights, practical experiences, method development to applications of capillary and microchip electrophoresis. The focus will be given to discussions between the participants instead of pure lectures. Participants are also encouraged to present negative results of their research efforts or share unresolved hypotheses with the audience.